Nematic Director Orientation in a Liquid-Crystal-Dispersed Polymer - A Deuterium NMR Approach

نویسندگان

  • Ralf Stannarius
  • G. P. Crawford
  • Liang-Chy Chien
  • William Doane
  • J. W. Doane
چکیده

The nuclear-magnetic-resonance (NMR) technique is employed to liquid-crystal-dispersed-polymer (LCDP) systems. Deuterium NMR is used to determine director distributions in LCDP cells in the presence of a magnetic field. The samples consist of a nematic liquid crystal mixed with small percentages of a monomer that is polymerized under different conditions after dissolving it in the liquid crystal. NMR spectra of the deuterated liquid-crystal molecules give information on orientation and order in such systems. The orientation of the polymer skeleton formed during the polymerization is found to be stable. It determines the orientation of the nematic director even in the presence of a strong external magrietic field. Simple models for the director field aie presented.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Biaxial nematic phase in a thermotropic liquid-crystalline side-chain polymer.

We report on variable-angle deuterium NMR measurements of nematic liquid-crystalline side-chain polymers, where we have found proof of the existence of a biaxial nematic phase in a system with a side-on attachment of the mesogenic group to the polymer backbone. This provides efficient coupling to the polymer backbone and thus stabilizes the as yet elusive biaxial phase. The experimental approac...

متن کامل

Deuteron NMR study of molecular ordering in a holographic-polymer-dispersed liquid crystal.

Using deuteron nuclear magnetic resonance (NMR) and dynamic light scattering, we study the orientational order and dynamics of a BL038-5CB liquid-crystal mixture in a holographic polymer dispersed liquid-crystal material (HPDLC) as used for switchable diffractive optical elements. At high temperatures, where the liquid crystal is predominantly in the isotropic phase, the HPDLC deuteron NMR line...

متن کامل

Preparation of a Mechanochromic Elastomer using Liquid Crystal Dispersed in Polymer

We have designed an inexpensive and sensitive mechanochromic system. Our system is prepared by a simple emulsion procedure of nematic liquid crystal in polydimethylsiloxane (PDMS). The resulting polymer dispersed liquid crystal (PDLC) exhibits a transmission change of 50% as a response to strain. Here we characterize the morphological, optical, and mechanical factors behind this transmission ch...

متن کامل

Xenon NMR Study of a Nematic Liquid Crystal Confined to Cylindrical Submicron Cavities

NMR studies of xenon gas dissolved in the liquid crystal ZLI 1132 confined to submicron cylindrical cavities are reported. Spectra taken as a function of temperature yield a clear indication of the nematic to isotropic phase transition of the confined liquid crystals. In the nematic phase at 21 "C, the resonance line of dissolved 129Xe exhibits a chemical shift anisotropy of 15 ppm due to a ran...

متن کامل

Phase switching of ordered arrays of liquid crystal emulsions

Polymer dispersed liquid crystals (PDLC) are a well established technology for electrooptic devices used in displays and light switches. They rely on dispersions of nematic liquid crystal material in a polymer matrix. In the absence of an electric field, the director field n(r), which characterizes the local average orientation of the rodlike nematic mesogens, is randomly oriented, leading to a...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2016